IL PRESIDENTE PROF. PIETRO
TUNDO

Biografia
Interessi di ricerca e attivitą
Publications
Patents (Brevetti)
Gruppo di ricerca
Relazione 2005-2007.pdf
Report Research Group 2007 (PDF Format)
Report Research Group 2006 (PDF format)
Report Research Group 2005 (PDF format)
Report
Research Group 2004 (PDF format)
Report Research Group 2003 (PDF format)
Report Research Group 2002 (PDF format)
Report Research Group 2001 (PDF format)
Laurea in Chimica all'Università di Bologna
(1969). Pietro Tundo è stato ricercatore
(1972-1983) e poi professore associato (1983-1986)
all'Università di Torino e all'Università
di Messina (1986-1989).
Dal 1989 è professore ordinario di chimica
organica all'Università Ca' Foscari di
Venezia.
È stato ricercatore negli USA (Research
Associate, Senior Research Associate) alla University
of College Station (Texas: 1979-1981), Potsdam
(New York: 1989-1990) and Syracuse (New York:
1991 - 1992).
Pietro Tundo è il fondatore e Presidente
del Consorzio Interuniversitario "la Chimica
per l'Ambiente " (INCA: 1993).
È chairman del Working Party on "Synthetic
Pathways and Processes in Green Chemistry",
della IUPAC Commission III/2.
È stato insignito del premio Federchimica
"Un fututo intelligente", e del ACS'
Kendall Award (1983) con Janos Fendler.
È membro del OECD Issue Team for the Sustainable
Chemistry Program.
È autore di circa 150 pubblicazioni scientifiche
e 25 brevetti.
È autore unico del libro "Continuous
flow methods in organic synthesis" E. Horwood
Pub., Chichester, UK, 1991 (378 pp.)
| Interessi
di ricerca e attività |
|
* Nuove reazioni del dimetilcarbonato
e loro meccanismo
* Idrodealogenazione in condizioni multifasiche
* Sintesi di fullereni funzionalizzati e loro
films di Langmuir-Blodget
* Reazioni di sostituzione nucleofilo in CO2 supercritica
ATTIVITÀ ACCADEMICHE
* Eletto presidente del Consorzio Interuniversitario
Nazionale "La Chimica per l'Ambiente"
nel Gennaio 2001
| ATTIVITÀ EDITORIALI Internazionali: |
|
* Green Chemistry, RSC (Int. Ed. Board)
* Environmental Science and Pollution Research,
Ecomed Publishers (Ed. Board)
* Reactive Polymers, Elsevier (Ed. Board)
* Clean Products and Processes, Springer (Ed.
Board)
| ATTIVITÀ EDITORIALI Nazionali: |
|
* Notiziario del Consorzio Interuniversitario
Nazionale "La Chimica per l'Ambiente"
"Chimica News Ambiente", (Direttore
Responsabile).
* La Chimica e l'Industria, Editrice Bias S.a.s.
(Ed. Board).
* Piano del Consorzio:
Piano "Ambiente Terrestre: Chimica per l'Ambiente"
( Cluster C11-A
* Laboratorio INCA di Marghera:
a) Laboratorio Analitico di Microinquinanti Organici
b) Laboratorio di Green Chemistry
c) Laboratorio di Microbiologia Ambientale Applicata
Nel 2000 è iniziato il
progetto biennale NATO CLG intitolato "New
Chemical Detoxification Methods for Hazardous
Halo-Aromatic Pollutants" in cooperazione
con gruppi di ricerca dello Zelinsky Institute
of Organic Chemistry e dello Sevetsov Institute
of Ecology and Evolution Problems dell'Accademia
Russa delle Scienze di Mosca.
Nel 2001 un progetto biennale
INTAS dal titolo "New Catalytic Methods for
the Degradation of Polychlorinated Organic Pollutants"
è iniziato assieme ai due gruppi del progetto
NATO e con i gruppi della Moscow State University
e della Munich Technical University.
I gruppi di ricerca coinvolti mostrano ottime
potenzialità di ricerca attinenti al tema
scientifico delle tecniche chimiche rivolte al
problema globale della detossificazione di inquinanti
organici clorurati, ad esempio composti come le
diossine, i PCB, ecc.
European Postrgraduate Summer
School on Green Chemistry, Venezia, annuale 1998-2004.
* IUPAC-OECD Workshop on Green Chemistry Education,
Venice 12-14 September 2001.
* Corso di Formazione "Nuovi Processi e Prodotti
Eco-compatibili per lo sviluppo aziendale"
Regione Veneto.
COLLABORAZIONI
* North Carolina, USA, NSF-Center for Environmentally
Responsible Solvents located at the University
of North Carolina at Chapell Hill
* EUROPEAN COMMISSION, COST ACTION D29 :"Sustainable/Green
Chemistry and Chemical Technology"
* Organization for Economic Co-operation and Development
(OECD), Sustainable Chemistry Program
SOCIO DI:
* Società Chimica Italiana
* American Chemical Society
* IUPAC
ATTIVITÀ IUPAC
* Chairman del Interdivisional Sub-Committee on
Green Chemistry
* Chairman del Working Party on Synthetic Pathways
and Processes in Green Chemistry
1. Caglioti, L.; Rosini, G.; Tundo,
P. and Vigevani, A.: "The Reaction of Arylazoalkanes
with Dienophilic Compounds", Tetrahedron
Letts., 1970, 2349-2352.
2. Degani, I.; Fochi, R. and Tundo, P.: "Pentaatomic
Heteroaromatic Cations. Note I. Synthesis of Some
2-Aryl-1,3- Benzoxathiolium Perchlorates",
Ann. Chim., Roma, 1972, 62, 570-574.
3. Degani, I.; Fochi, R. and Tundo, P.,: "Pentaatomic
Heteroaromatic Cations. Note II. Chemical Properties
of 2- Phenyl-1,3-Benzoxathiolium Perchlorate",
J. Heter. Chem., 1974, 11, 507-510.
4. Degani, I.; Fochi, R., Tundo, P. and Costa,
L.: "Pentaatomic Heteroaromatic Cations.
Note III. A Covenient Synthesis of Aldeydes from
Carboxylic Acids via 2-Substituted-1,3- Benzoxathiolium
Perchlorates", J. Hether. Chem., 1974, 11,
943-948.
5. Degani, I.; Fochi, R. and Tundo, P.: "Pentaatomic
Heteroaromatic Cations. Note IV. A Convenient
Synthesis of Ketones from Carboxylic Acids via
2-Substituted-1,3- Benzoxathiolium Perchlorates",
Gazz. Chim. It.,1975, 105, 907-917.
6. Cinquini, M.; Montanari, F. and Tundo, P.:
"Alkyl Substituted
Aza-Macrobicyclic Polyethers: Highly Efficient
Catalysts in Two- Phase Reactions", J. Chem.
Soc., Chem. Commun., 1975, 393-394.
7. Fornasier, R.; Montanari, F.; Podda, G. and
Tundo P.: "Polypode Ligands as Phase-Transfer
Catalysts", Tetrahedron Letts., 1976, 1381-1384.
8. Cinquini, M.; Colonna, S.; Molinari, H.; Montanari
F. and Tundo P.:"Heterogeneous Phase-Transfer
Catalysts: Onium Salts, Crown Ethers, and Cryptands
Immobilized on Polymeric Supports", J. Chem.
Soc., Chem. Commun.,1976, 394-396.
9. Cinquini, M. and Tundo, P: "Synthesis
of Alkyl-Substituted Crown Ethers: Efficient Phase-Transfer
Catalysts", Synthesis, 1976, 516-518.
10. Cinquini, M.; Montanari, F. and Tundo, P.:
"Phase-Transfer Catalysts: Synthesis and
Catalytic Activity of Alkyl Substituted Aza-Macrobicyclic
Polyethers", Gazz. Chim. It., 1977, 107,
11-14.
11. Molinari, H.; Montanari F. and Tundo P.: "Heterogeneous
Phase-Transfer Catalysts: High Efficacy of Catalysts
Bonded by a Long Chain to a Polymeric Matrix",
J. Chem. Soc., Chem. Commun., 1977, 639-641.
12. Tundo, P.: "Silica Gel as a Polymeric
Support for Phase- Transfer Catalysts", J.
Chem. Soc., Chem. Commun., 1977, 641-642.
13. Tundo, P.: "Easy and Economical Synthesis
of Widely Porous Resins; Very Efficient Supports
for Immobilized Phase-Transfer Catalysts",
Synthesis, 1978, 315-316.
14. Tundo, P.: "Alkyl Substituted Tetraaza-Cycloalcanes:
Carriers of Transition Metal Ions in Organic Phase
and Catalysts of Anion PromotedReactions",
Tetrahedron Letts., 1978, 4693-4696.
15. Landini, D.; Maia, A.; Montanari, F. and Tundo,
P: "Lipophilic [2.2.2]Cryptands as Phase-Transfer
Catalysts. Activation and Nucleophilicity of Anions
in Aqueous-Organic Two- Phase Systems and in
Organic Solvents of Low Polarity", J. Am.
Chem. Soc., 1979, 101, 2526-2530.
16. Moroi, Y.; Pramauro, E.; Gratzel, M.; Pelizzetti,
E. and Tundo, P.:"Surface Activity and Micelle
Formation of Alkyl- Substituted Aza-Crown Ethers
and Their Metal Ion Complexes, J. Coll. Inter.
Sci., 1979, 69, 341-343.
17. Molinari, H.; Montanari, F.; Quici, S. and
Tundo, P.:"Heterogeneization of Phase-Transfer
Catalysts. High Catalytic Activity of Ammonium
anf Phosphonium Salts Bonded to a Polystyrene
Matrix", J. Am. Chem. Soc., 1979, 101, 3920-3927.
18. Tundo, P. and Venturello, P.: Synthesis, "Catalytic
Activity and Behavior of Phase-Transfer Catalysts
Supported on Silica Gel: Strong Influence of Substrate
Adsorption on the Polar Polymeric Matrix on the
Efficiency of the Immobilized Phosphonium Salts",
J. Am. Chem. Soc., 1979,
101, 6606-6613.
19. Tundo, P.: "Nucleophilic Substitution
Between a Gaseous Alkyl Halide and a Solid Salt
Promoted by Phase-Transfer Catalysts", J.
Org. Chem.,n 1979, 44, 2048-2049.
20. Tundo, P. and Venturello, P.: "Gas-Phase
Synthesis of Alkyl Iodides Promoted by Phase-Transfer
Catalyst", Synthesis, 1979, 952-954.
21. Humphry-Baker, R.; Gratzel, M.; Tundo, P.
and Pelizzetti, E.: "Photochemical and Thermal
Redution od Silver Ions in Aza- Crown Ethers Surfactants;
Formation of Stable Silver Atoms", Angew.
Chem. Int. Ed. Eng., 1979, 18, 630-631.
22. Montanari, F. and Tundo, P.: "Hydroxymethyl-18-Crown-6
and Hydroxymethyl [2.2.2]Cryptand: Versatile Intermediates
for Binding the Two Polyethers to Lipophilic Chains
and to Polymer Matrices", Tetrahedron Letts.,
1979, 5055-5058.
23. Tundo, P. and Fendler, J. H.: "Photophysical
Investigation of Chiral Recognition in Crown Ethers",
J. Am. Chem. Soc., 1980, 102, 1760-1762.
24. Tundo, P. and Venturello, P.: "Silica
Gel Supported Onium Salts as Micellar and Phase-Transfer
Catalysts", Tetrahedron Letts., 1980, 2581-2584.
25. Humphry-Baker, R.; Moroy, Y.; Gratzel, M.;
Pelizzetti, E. and Tundo, P.: "Photoinduced
Processes in Copper(II)-Crown Ether Surfactant
Micelles", J. Am. Chem. Soc., 1980, 102,
3689-3692.
26. Monserrat, K.; Gratzel, M. and Tundo, P.:
"Light Induced Injection In Functional Crown
Ether Vesicles", J. Am. Chem. Soc., 1980,
102, 5527-5529.
27. Angeletti, E.; Tundo, P. and Venturello, P.:
"Catalytic Halide Exchange in Hydrocarbons
Promoted by Aluminas Coated with Phosphonium Salts",
J. Chem. Soc., Chem. Commun., 1980, 1127- 1128.
28. Tundo, P. and Venturello, P.: "Catalysis
Mechanism of Phosphonium Salts Supported on Silica
Gel in Aqueous-Organic Two-Phase System",
J. Am. Chem. Soc., 1981, 103, 856-861.
29. Montanari, F. and Tundo, P.: "Polymer-Supported
Phase- Transfer Catalysts. Crown Ethers and Cryptands
Bonded by a Long Chain to a Polystyrene Matrix",
J. Org. Chem., 1981, 46, 2125-2130.
30. Tze-chi, J.; Bernard, G. S.; Tundo, P. and
Fendler, J. H.: "Stabilization of Colloidal
Silver Produced by Pyrene Sensitized Photoreduction
of Silver Ions", J. Phys. Chem., 1981, 85,
1963-1967.
31. Tundo, P.; Kippenberger, D. J.; Klahan, P.;
Prieto, N. E.; Tze-chi, J. and Fendler, J. H.:
Functionally Polymerized Surfactant Vesicle.
Synthesis and Characterization", J. Am. Chem.
Soc., 1982, 104, 456-461.
32. Angeletti, E.; Tundo, P. and Venturello, P.:
"Synthetic and Mechanistic Aspects of Gas-Liquid
Phase-Transfer Catalysis: Carboxylate Esters",
J.Chem. Soc., Perkin Trans. I, 1982, 993- 997.
33. Tundo, P.; Kurihara, K.; Kippenberger, D.
J.; Politi, M. and Fendler J.H.: "Chemically
Dissimmetrical, Polymerized Surfactant Vesicles:
Synthesis and Possible Utilization in Artificial
Photosynthesis", Angew. Chem. Int.Ed. Engl.,
1982, 21. 81- 82.
34. Tundo, P.; Kippenberger, D. J.; Politi, M.;
Klahan, P. and Fendler J.H.: "Redox Active
Functionally Polymerized Surfactant Vesicles.
Synthesis and Characterization", J. Am. Chem.
Soc., 1982, 104, 5352-5358.
35. Tundo, P.; Venturello, P. and Angeletti, E.:
"Anion-Exchange Properties of Ammonium Salts
Immobilized on Silica Gel, J. Am. Chem. Soc.,
1982, 104, 6547-6551.
36. Tundo, P.; Venturello, P. and Angeletti, E.:
"Phase-Transfer Catalysts Immobilized and
Adsorbed on Alumina and Silica Gel", J. Am.
Chem. Soc., 1982, 104, 6551-6555.
37. Montanari, F. and Tundo, P.: "Hydroxymethylderivatives
of 18- Crown-6 and [2.2.2]Cryptand: Versatile
Intermediates for the Synthesis of Lipophilic
and Polymer-Bonded Mocrocyclic Ligands",
J. Org. Chem., 1982, 47, 1298-1302.
38. Angeletti, E.; Tundo, P. and Venturello, P:
"Gas-Liquid Phase-Transfer Catalysis of Phenyl
Ethers and Sulphides with Carbonate as a Base
and Carbowax as a Catalyst", J. Chem. Soc.,
Perkin Trans I, 1983, 1137-1141.
39. Angeletti, E.; Tundo, P. and Venturello, P.:
"Catalytic Interconversion of Alkyl Halides
by Gas-Liquid Phase-Transfer Catalysis",
J. Chem. Soc., Perkin Trans. II, 1983, 485-491.
40. Angeletti, E.; Rubbo, M.; Tundo, P. and Venturello,
P.: "Crystal Growth of Alkali Metal Halides
during the Gas-Liquid Phase-Transfer Catalysis",
J. Chem. Soc., Perkin Trans. II, 1983, 493-495.
41. Montanari, F.; Quici, S. and Tundo, P.: "Mechanism
of Reaction Promoted by Polymer-Supported Phase-Transfer
Catalysts", J. Org. Chem., 1983, 48, 199-202.
42. Angeletti, E.; Tundo, P. and Venturello, P.:
"The Wittig Synthesis of Alkenes under Gas-Liquid
Phase-Transfer Catalysis", J. Chem. Soc.,
Chem. Commun., 1983, 269-281.
43. Kippenberger, D. J.; Odberger, L.; Tundo,
P. and Fendler, J. H.: "Polymeric Surfactant
Vesicles. Synthesis and Characterization by Nuclear
Magnetic Resonance and Dynamic Light Scattering",
J. Am. Chem. Soc., 1983, 105, 1129-1135.
44. Kurihara, K.; Tundo, P. and Fendler J. H.:
"Aspects of Artificial Photosynthesis. Photosensitized
Electron Transfert and Charge Separation in Redox
Active Surfactant Aggregates", J. Phys. Chem.,
1983, 87, 3777-3782.
45. Angeletti, E.; Tundo, P. and Venturello, P.:
"Gas-Liquid Phase-Transfer Catalysis: Catalytic
and Continuous Transesterificatioin Reaction",
J. Org. Chem., 1983, 48, 4106-4109.
46. Reed, W.; Guterman, L.; Tundo, P. and Fendler,
J. H.: "Polymerized
Surfactant Vesicles. Kinetics and Mechanism of
Photopolymerization", J. Am. Chem. Soc.,
1984, 106, 1897-1907.
47. Nome, F.; Reed, W.; Politi, M.; Tundo, P.
and Fendler, J. H.: "Cleft Formation upon
Polymerization of Surfactant Vesicles", J.
Am. Chem. Soc., 1984, 106, 8086-8093.
48. Di Casa, M.; Fabbrizzi, L.; Perotti, A.; Poggi,
A. and Tundo, P.: "Specific Transport of
Copper (II) Ions Across a Liquid Membrane Mediated
by a Lipophilic Tetraaza Macrocycle", Inorg.
Chem., 1985, 24, 1610-1611.
49. Tundo, P.; Facchetti, S.; Tumiatti, W. and
Fortunati, U. G.: "Chemical Degradation of
2,3,7,8-TCDD by Means of Polyethyleneglycols in
the Presence of Weak Bases and an Oxidant",
Chemosphere, 1985, 14, 403-410.
50. Rafaeloff, R.; Tricot, M.; Nome, F.; Tundo,
P. and Fendler, J. H.: "Incorporation of
a Reciclable Surfactant-Active Electron Donor
in Synthetic Vesicles: Application to Photosensitized
Hydrogen Formation by Vesicle-Stabilized Rh- Coated
Colloidal Cds Particles", J. Phys. Chem.,
1985, 89, 1236-1238.
51. Tundo, P.: "PCBs, PSDFs, PCDDs: Chemical
Decontamination of Toxic Halogenated Aromatic
Compounds", Tecnologie Chimiche, 1986, 6
(5), 96-100.
52. Serrano, J.; Mucino, S.; Millan, S.; Reynoso,
R.; Fucugauchi, L. A.; Nome, F.; Tundo, P. and
Fendler, J. H.: "Polymerized Surfactants
Vesicles.
Determination of Rates and Degrees of Polymerization
in Vesicles Prepared from Styrene- Containing
Surfactants", Macromolecules, 1985, 18, 1999-2005.
53. Tundo P. and Paruccini, M.: "Computer
in Chemical Emergency", Tecnologie Chimiche,
1986, 6 (5), 86-89.
54. Guarini, A. and Tundo, P.: "Rose-Bengala
Functionalized Phase-Transfer Catalysts Promoting
Photooxidation with Singlet Oxygen", J. Org.
Chem., 1987, 52, 3501-3508.
55. Trotta, F.; Tundo, P. and Moraglio, G.: "Selective
Mono-N- Alkylation of Aromatic Amines by Dialkylcarbonates
under Gas- Liquid Phase-Transfer Catalysis",
J. Org. Chem., 1987, 52, 1300-1304.
56. Angeletti, E.; Tundo, P. and Venturello, P.:
"Gas-liquid Phase-Transfer Catalysis, Wittig-Horner
Reaction in Heterogeneous Conditions", J.
Chem. Soc., Perkin Trans. I, 1987, 713-714.
57. Tundo, P.; Venturello, P. and Angeletti, E.:
"Malonic Acetoacetic and Acetylacetonic Alkylation
Reactions by Gas-Liquid Phase-Transfer Catalysis
(GL-PTC)", J. Chem. Soc., Perkin Trans. I,
1987, 2159-2162.
58. Tundo, P.; Venturello, P. and Angeletti, E.:
"Continuous Conversion of Alcohols into Alkyl
Halides by Gas-Liquid Phase-Transfer Catalysis
(GL-PTC)", J. Chem. Soc., Perkin Trans. I,
1987, 2157-2158.
59. Tundo, P.; Trotta, F., Moraglio, G. and Ligorati,
F.: "Continuous-Flow Processes Under Gas-Liquid
Phase-Transfer Catalysis (GL-PTC) Conditions:
The Reaction of Dialkyl Carbonates with Phenol,
Alcohols, and Mercaptants", I&EC Research,
1988, 27, 1565-1571.
60. Tundo, P.; Trotta, F. and Moraglio.: "Kinetic
Study on Exchange Reaction of Alkyl Halides Under
Gas-Liuid Phase-Transfer Catalysis", J. Chem.
Soc., Perkin Trans II, 1988, 1709-1712.
61. Tundo, P.; Trotta, F. and Moraglio, G.: "Selective
and Continuous-Flow Mono-Alkylation of Aryl Acetonitriles
and Malonate Esters With Dialkyl Carbonates, Under
Gas-Liquid Phase- Transfer Catalysis", J.
Chem. Soc., Perkin Trans I, 1989, 1070-1071.
62. Tundo, P. and Badiali, M.: "High Activity
in Displacement Reactions by Quaternary Onium
Salts Immobilized on Inorganic Matrices",
Reactive Polymers, 1989, 10, 55-65.
63. Tundo, P.; Moraglio, G. and Trotta, F.: "Gas-Liquid
Phase-Transfer Catalysis: A New Continuous-Flow
Method in Organic Synthesis", I&EC Research,
1989, 25, 881-890.
64. Tundo, P.; Trotta, F. and Moraglio, G.: "Reactions
of Dimethyl Carbonate with Nucleophiles under
Gas-Liquid Phase-Transfer Catalysis (GL-PTC) Conditions",
Reactive Polymers, 1989, 10, 185-188.
65. Yuan, Y.; Tundo, P. and Fendler, J. H.: "Photopolymerization
of Vesicles Preparerd from n-Hexadecyl 11-(4-Vinylbenzamide)undecyl
Hydrogen Phosphate and from Mixtures of Dioctadecyldimethylammonium
Bromide and n-Hexadecyl 11-(4- Vinylbenzamide)undecyl
Hydrogen Phosphate", Macromolecules, 1989,
22, 29-35.
66. Ruggeri, B.; Tundo, P. and Tumiatti, W.: "Supported
Liquid Phase Reactor (SLPR) for PCBs in Oil Decontamination",
Chem. Eng. Sci., 1990, 45, 2687-94.
67. Selva, M.; Trotta, F. and Tundo, P.: "Improved
Selectivity in Chloromethylation of Alkyl Benzenes
Carried out in the Presence of Quaternary Ammonium
Salts", Synthesis, 1991, 1003.
68. Selva, M.; Trotta, F.; Tundo, P.: "Mono-methylation
of activated esters and thiophenol with different
alkylating agents under gas-liquid phase-transfer
catalysis (GL-PTC) conditions" ; Chimica
& Industria 1991, 73, 919.
69. Selva, M.; Trotta, F. and Tundo, P.: "Esters
and Orthoesters as Alkylating Agents at High emperature.
Application to Continuous-flow Processes",
J. Chem. Soc., Perkin Trans. I, 1992, 519-522.
70. Selva, M.; Trotta, F. and Tundo, P.: "Mono-methylation
of Activated Esters with Dimethylcarbonate by
Gas-liquid Phase- Transfer Catalysis (GL-PTC).
The Reactions of Thiophenol with Methyl Esters".,
Chim. & Ind., Milano, 1992, 918.
71. Tundo, P., Hodge, P. and Valli, L.: "Langmuir-Blodgett
Films Prepared from Preformed Cholestanic Liquid-crystalline
Polymers", Chim. & Ind., Milano, 1992,
72. Rolandi, R.; Gussoni, A.; Maga, L.; Robello,
M. and Tundo, P.:"Two-Dimensional Structures
in Polymerized Monomolecular Films", Thin
Solid Films, 1992, 412, 210-211.
73. Tundo, P.; Marques, C. A. and Selva, M.: "Hydrodehalogenation
of Polychlorinated Aromatics with Pd/C Catalyst
Under Multiphase Conditions", Rend. Fis.
Acc. Lincei, 1992, Serie 9, 3, 283-294.
74. Marques, C. A.; Selva, M. and Tundo, P., "Hydrodehalogenation
of Polychlorinated Aromatics by Hypophosphite
with Pd/C Catalyst under Multiphase Conditions",
J. Chem. Soc., Perkin Trans.1, 1993, 529-533.
75. Marques, C. A.; Selva, M. and Tundo, P.: "Facile
Hydrodehalogenation with Hydrogen and Pd/C Catalyst
under Multiphase Conditions", J. Org.Chem.,
1993, 58, 5256-5260.
76. Selva, M.; Marques, C. A. and Tundo, P.: "The
Addition Reaction of Dialkyl Carbonates to Ketones",
Gazz. Chim. It., 1993, 123, 515-518.
77. Marques, C. A.; Selva, M.; Tundo, P. and Montanari,
F.: "The Reaction of Oximes with Dimethylcarbonate:
A New Entry to 3-Methyl-4,5- disubstituted-4-oxazolin-2-ones",
J. Org. Chem., 1993, 58, 5765- 5770.
78. Selva, M.; Trotta, F. and Tundo, P.: "Polyethylene
Glycols as Phase-transfer Catalysts: Their Utilization
in Gas-liquid Phase- transfer Catalysis and in
the Reaction of Polychlorinated Biphenils",
Polymeric Materials Science and Engineering, 1993,
69, 472-473.
79. Selva, M.; Marques, C. A. and Tundo, P., "Facile
Hydrodehalogenation with H2 and Pd/C Catalyst
under Multiphase Conditions, Part II", J.
Org. Chem., 1994, 59, 3830-3837.
80. Loosen, P.; Selva, M.; Volckaerts, E.: "L'impiego
del dimetilcarbonato come agente metilante altamente
selettivo nella preparazione di intermedi per
farmaci antiinfiammatori"; in Processi Chimici
Innovativi e Tutela dell'Ambiente, Venezia, 1994,
100-109.
81. Cavalleri, O.; Leporatti, S.; Rolandi, R.
and Tundo, P.: "Polymeric Separated Phase
in onomolecular Films Revealed by Scanning Force
Microscopy"; Langmuir, 1994, 10, 1334-1336.
82. Marques, C. A.; Selva, M. and Tundo, P.: "Selective
Mono- Methylation of Arylacetonitriles and Methyl
Arylacetates by Dimethylcarbonate", J. Chem.
Soc., Perkin 1, 1994, 1323-1328.
83. Ahluwalia, A.; Carra, M.; De Rossi, D.; Ristori,
C.; Tundo, P. and Bomben, A.: "Improvement
of antibody surface density by orientation of
reduced fragments", Thin Solid Films, 1994,
247, 244-247.
84. Marques, C.A.; Selva, M.; Rogozhnikova, O.
and Tundo, P.: "Selectivities in the hydrodehalogenation
of polychloro and polybromobenzenes", J.
Mol. Catal., 1995, 96, 301-309.
85. Selva, M.; Tundo, P. and Marques, C.A.: "A
simple one-pot synthesis of funcionalized ketimines
from ketones and amine and hydrochlorides salts".
Synthetic Commun., 1995, 25, 369-378.
86. Marques, C. A.; Selva, M. and Tundo, P.: "Facile
Hydrodehalogenation with Hydrogen and Pd/C Catalyst
under Multiphase Conditions. 3. Selective Removal
of Halogen from Functionalized Aryl Ketones".
J. Org. Chem., 1995, 60, 2430-2435.
87. Marques, C. A.; Selva, M. and Tundo, P.: "Facile
Hydrodehalogenation with Hydrogen and Pd/C Catalyst
under Multiphase Conditions. 4. Aryl Halide-Promoted
Reduction of Benzyl Alcohols to Alkanes".
J. Org. Chem.,1995, 60, 2430-2435.
88. Tundo, P.; Selva, M.: "Simplify gas-liquid
phase transfer catalysis", Chemtech, 1995,
25(5), 31-35.
89. Selva, M.; Marques, C.A.;, Tundo, P.: "Selective
Mono-Benzylation of Methylene Active Compounds
with Dibenzylcarbonate. Benzylation of Phenol",
J. Chem. Soc., Perkin Trans. I, 1995, 1889-1893.
90. Selva, M.; Tundo P.: "Gas-Liquid Phase-Transfer
Catalysis (GL-PCT)", Chimica & Industria,
1995, 77, 411-414.
91. Selva, M.; Tundo P.:"Gas-Liquid Phase
Transfer Catalysis Reaction of Dialkyl Carbonates",
La Chimica & L'Industria, 1995, 77, N°
10, 763-766.
92. Bomben, A.; Marques C. A.; Selva M.; Tundo
P.: "A New Synthesis of 2-Aryloxy propionic
Acids Derivates via Selective Mono-C-Methylation
of Methyl Aryloxy acetates Aryloxyacetonitriles
with DimethylCarbonate", Tetrahedron, 1995,
Vol. 51, 42, 11573-11580.
93. Rolandi, R.; Dante, M.; Grussoni, A.; Leporatti,
S.; Maga, L. and Tundo P.: "Polymerized Monomolecular
Films: Microscopic Structure, Viscosity, and Photopolimerization
Kinetics", Langmuir, 1995, 3119-3129.
94. Tundo, P.; Selva, M., "Selective Mono-Methylation
of Arylacetonitrilesn and Methyl Arylacetates
by Dimethylcarbonate: A Process without Production
of Wastes" In Designing Chemical Synteheses
and Processes, Anastas, P.; Williamson, T., Eds.,
ACS Symposium Series No. 626, 1996; Ch. 7, 81-91.
95. Marques, C.A.; Selva, M.; Tundo, P.: "Hydrodehalogenation
of Polyhalogenated Aromatics under Multiphase
Conditions with H2 and Metal Catalyst: Kinetics
and Selectivity" Gazz. Chim. It., 1996, 126,
317-327.
96. Ali-Abib, Z.; Bomben, A.; Davis, F.; Hodge,
P.; Tundo P. and Valli, L.: "Examples of
Amphitropic Polymers: Monolayer Film, Langmuir-Blodgett
Film and Liquid Crystal Properties of some Polymeric
Amphiphiles containing Cholestanol Moieties and
those of some closely related Non-Polymeric
Amphiphiles" J. Material Chem., 1996, 6(1),
15-22.
97. Bomben A.; Selva, M.; Tundo, P.: " The
Use of Dialkyl Carbonates for Safe and Highly
Selective Alkylation of Methylene-Active Compounds.
A Process without the Production of Wastes",
Recueil des Travaux Chimiques des Pays-Bas, 1996,
115, 256-260.
98. Bomben A.; Marques, C. A.;Selva, M.; Tundo,
P.: "Synthesis of Substituted Phenones via
Pd-Catalysed Hydrodechlorination fo their Polychlorinated
Dervatives", Synthesis, 1996, 9, 1109-1114.
99. M. Selva, A. Bomben, P. Tundo "Selective
Mono-N-methylation of Primary Aromatic Amines
by Dimethylcarbonate over Faujasite X- and Y-type
Zeolites", J. Chem. Soc., Perkin Trans 1,
1997, 1041-1045.
100. M. Selva, A. Bomben, P. Tundo "Dimethylcarbonate
as a Methylating Agent. The Selective Mono-C-methylation
of Alkyl Aryl Sulfones", Chem. Res. (M),
1998, 2688-2696.
101. M. Selva, P. Tundo, A. Perosa "Hydrodehalogenation
of Polyhalogenated Aromatic Ketones under Multiphase
Conditions. Part V. Chemoselectivity towards Bensylic
Alcohols over a Pt/C Catalyst" J. Org. Chem.,
1998, 63, 3266-3271.
102. M. Selva and P. Tundo "Dimethylcarbonate
as a Methylating Agent: a New Perspective for
Safe and Highly Selective Mono-N- and Mono-C-Alkylations"
In Green Chemistry: Frontiers in Benign Chemical
Synthesis and Processing, Oxford Press University,
Oxford: 1998, Ch. 5, pp. 87-100.
103. P. Tundo, M. Selva, and A. Bomben "Mono-C-Methylation
of Arylacetonitriles and Methyl Arylacetates by
Dimethylcarbonate: A General Method for The Synthesis
of Pure 2-Arylpropionic Acids", Org. Synth.,
1998, 76, 167-177.
104. M. Selva, P. Tundo "Trimethyl Orthoformate
as a Highly Selective Mono-C-methylating Agent
of Arylacetonitriles" J. Org. Chem., 1998,
63, 9540-9544.
105. M. Selva, A. Bomben, P. Tundo "Sy~thesis
of Alkylaryl and Diarylnitriles form Ketones via
N-(1-arylalkylidene)-cyanomethyl Amines"
Synth. Commun. 1999, 29(9), 1561-1569.
106. A. Bomben, M. Selva, P. Tundo and L. Valli:
"A Continuous-Flow O-Methylation of Phenols
with Dimethylcarbonate in a CSTR system",
1999, 38, 2075-7079.
107. A. Perosa, M. Selva and P. Tundo: "Efficient
synthesis of N-Alkylformimidoyl Cyanides",
etrahedron Letts., 1999, 40, 7573-7576.
108. A. Perosa, M. Selva and P. Tundo: "Hydrodehalogenation
of Halogenated Arylketones under Multiphase Conditions.
Part VI. PH-Effect on the Chemoselectivity and
Mechanistic Hypothesis", J. Org. Chem., 1999,
64, 3934-3939.
109. A. Perosa, M. Selva and P. Tundo: "The
Synthesis of Alkyl aryl nitriles from N-(1-arylalkylidene)-
cyanomethyl amines; some mechanistic conclusions".
J. Chem. Soc. Perkin Trans. 2, 1999, 2485-2492.
110. A. Perosa, M. Selva, P. Tundo and F. Zordan:
"Alkyl Methyl Carbonates as Methylating Agents.
The 0-Methylation of Phenosl". Synlett, 2000,
272-244.
111. S. Memoli, M. Selva and P. Tundo: "Dimethylcarbonate
as a Green Reagent" In Green Chemical Synthesis
and Processes, P. Anastas, L. G. Heine, T. Williamson,
Eds., ACS Symposium Series 767, 2000, Ch. 8, pp.
87-99.
112. A. Perosa, P. Tundo and S. Zinovyev: "Multiphase
Catalytic Hydrogenation of p-Chloroacetophenone
and Acetophenone. A kinetic Study of the Reaction
of Different Functional Groups". Journal
of Catalysis, 2000, 196, 330-338.
113. P. Anastas, D. Black, J. Breen, T. Collins,
S. Memoli, J. Miyamoto, M. Polyakoff, W. Tumas
and P. Tundo: "Synthetic pathways and processes
in green chemistry. Introductory overview*".
Pure Appl. Chem., 2000, Vol. 72, No. 7, 1207-1228.
114. P. Tundo: "Selective monomethylation
reactions of methylene-active compounds with dimethylcarbonate.
An example of clean synthesis*". Pure Appl.
Chem., 2000, Vol. 72, No. 9, 1793-1797.
115. S. Memoli, M. Selva and P. Tundo: "Dimethylcarbonate
for eco-friendly methylation reactions".
Chemosphere, 2001, 43, 115-121.
116. J. DeSimone, M. Selva, P. Tundo: "Nucleophilic
Displacements in Supercritical Carbon Dioxide
Using Silica-Supported Phase-Transfer Agents".
Journal of Organic Chemistry, 2001, Vol. 66, No.
11, 4047-4049.
117. A. Perosa, M. Selva, P. Tundo: "Reaction
of Primary Aromatic Amines with Alkyl Carbonates
over NaY Faujasite: A Convenient and Selective
Access to Mono-N-alkyl Anilines. The ounal of
Organic Chemistry, 2001, Vol. 66, No. 3, 677-680
118. P. Tundo, A. Perosa, M. Selva and S. Zinovyev,
"A New Mild Detoxification Method for PCDDs
and PCDFs" Appl.Catal. B: Environ. 2001,
32, L1-L7.
119. P. Tundo, A. Perosa, M. Selva, L. Valli and
C. Giannini: "Peptide anchored Langmuir-Blodgett
Films of a Fullerene Amphiphile" Colloids
and Surfaces, A: Physicochem. and Eng. Asp. 2001
190, 295-303.
120. P. Tundo, A. Perosa and L. Valli: "Recent
Developments in Langmuir-Blodgett Films Containing
Fullerene Derivatives" Proceedings 1st International
symposium on Macro- and Supramolecular Architectures
and Materials (MAM-01): Biological and Synthetic
Systems, 11-14 April 2001, Kwangju, South Korea.
121. A. Perosa and P. Tundo: "Green Organic
Syntheses: OrganicCarbonates as Methylating Agents".
The Cehmical Record, accepted 8th August 2001,
TCR-0046
122. M. Selva and P. Tundo: "Dimethtl carbonate:
Chemistry and Reaction Mechanism". Accounts
of Chemical Research, Special Issue on Green Chemistry,
2001, in print.
123. M. Selva, A. Perosa, P. Tundo and S. Memoli,:
"Selective Mono-C-Methylations of Arylacetonitriles
and Arylacetates with Dimethylcarbonate: A mechanistic
Investigation" J. Org. Chem.2001, in print.
124. P. Tundo: "New Developments in Dimethyl
Carbonate Chemistry". Pure Appl. Chem, 2001,
in print.
125. A. Perosa and P. Tundo: "Green Organic
Syntheses: Organic Carbonates as Alkylating Agents"
Chem. Record 2001, in print.
126. A. Perosa, P. Tundo and M. Selva: "Multiphase
Heterogeneous Catalytic Enantioselective Hydrogenation
of Acetophenone Over Cinchona-Modified Pt/C"
J. Mol. Catal. A. Chem. 2001 in print.
127. A. Perosa, M. Selva and P. Tundo: "The
Synthesis of Alkyl Carbamates from Primary Aliphatic
Amines and Dialkyl Carbonates in
Supercritical Carbon Dioxide", Tetrahedon,
2001, in print.
128. P. Tundo: "A mechanistic Investigation".
The Journal of Organic Chemistry, 2001, in print.
129. P. Tundo: "Modern Synthetic Chemistry".
Pure Appl. Chem, 2001, in print.
130. D. Hérault, K. Hill, S. Memoli and
P. Tundo: "Synthesis of methylers by reaction
of alcohols with dimethylcarbonate", submitted.
131. M. Selva, P. Tundo and A. Perosa: "On
the mechanism whereby N-(1-arylalkylidene)-cyanomethylamines
[ArC(=NCH2CN)R] rearrange to alkyl aryl nitriles
(ArCH(CN)R)", submitted
132. S. Memoli: "Methylethers from the decarboxylation
of Mehylcarobates", submitted
REVIEWS
1. Fendler, J. H. and Tundo, P.: "Polymerized
Surfactant Aggregates: Characterization and Utilization",
Acc. Chem. Res., 1984, 16, 3-8.
2. Angeletti, E.; Tundo, P. and Venturello, P.:
"Quaternary Onium Salts Immobilized on Inorganic
Matrices", Isr. J. Chem., 1985, 26, 283-
290.
3. Tundo, P.: "Synthetic Strategies for Polymeric
Liposomes", Atti Accademia Nazionale dei
Lincei, 1985, 75-88.
4. Tundo, P. and Venturello, P.: "Synthetic
Reactions by Gas- Liquid Phase-Transfer Catalysis,
in "Crown Ethers and Phase- Transfer Catalysis
in Polymer Science", Plenum Publishing Corporation,
New York, 1984, 219-221.
5. Angeletti, E.; Tundo, P. and Venturello, P.:
"Synthetic Opportunities of Gas-Liquid Phase-Transfer
Catalysis", British Pol. Journal, 1984, 219-221.
6. Tundo, P.; Nobile, G. and Tumiatti, W.: "Chemical
Degradation of PCB, PCDF and PCDD by means of
Polyethers, a Base and an Oxidant (CDP-Processes),
in "Solving Hazardous Waste Problem",
ASC Symposium Series No. 338, Chap. 31, Am. Chem.
Soc., Washington D. C., 1987, pp. 376-383.
7. Tundo P., "Gas-Liquid Phase-Transfer Catalysis:
a New Method in Organic Synthesis", Gazz.
Chim. Ital. 1990, 120, 69-76.
BOOKS
1. Tundo, P. "Continuous Flow Methods in
Organic Synthesis", E. Horwood Pub.,
Chichester, UK, 1991.
2. P. Tundo, D. StC. Black, S. Memoli, Editors:
"Symposium-in-Print", IUPAC Pure and
Applied Chemistry, 2000, Vol. 72, 1229- 1403.
3. P. Tundo, Editor; L. Clemenza, A. Perosa, Co-Editors:
"Collection of Lectures of the Summer School
on Green Chemistry", Green Chemistry Series
n.1, Interuniversity Consortium Chemistry for
the Environment ISBN: 88 88214 00 3, 1998-1999-2000,
Venice, Italy. September 2001.
4. P. Tundo, Editor: "IUPAC-OECD Workshop
on Green Chemistry Education", Green Chemistry
Series n. 2, Interuniversity Consortium Chemistry
for the Environment, ISBN: 88 88214 00 4, 21st.
November 2001.
1. Tundo, P.: Phase Transfer Catalysts
Immobilized on Polystyrenic Resins Having a Large
Porosity. Italian Pat. Appl. N. 13245 A/77.
2. Tundo, P. : Process for a New Phase-Transfer
Catalysis Between a Gaseous Phase Constituted
by an Organic Substrate and a Solid Phase Containing
the Catalyst and a Salt. Italian Pat. Appl. N.
19294 A/78.
3. Fo M.; Gardano, A.; Francalanci, F. and Tundo,
P.: New Catalysts for Carbonylating Organic Halides,
Process for Their Preparation and Related Process
for Carbonolation. Italian Pat. Appl. N. 20283
A/83.
4. Tundo, P. and Venturello, P.: Continuous Process
in Gaseous Phase for the Converting Alcohols into
Alkyl Chlorides or Bromides with Aqueous Hydrochloric
or Hydrobromic Acid. Italian Pat. Appl. N. 22902
A/82.
5. Angeletti, E.; Tundo, P. and Venturello, P.:
Alkylation of CH-Acidic Compounds in Gas-Liquid
Phase-Transfer Catalysis Conditions. Italian Pat.
Appl. N. 23699 A/82.
6. Angeletti, E.; Tundo, P.; Venturello, P. and
Barberis, B.: Process in Gaseous Phase for the
Preparation of Onium Salts Immobilized on Inorganic
Matrices. Italian Pat. Appl. N. 24251 A/84.
7. Tundo, P.: Process for the Decomposition of
Toxic Halogenated Organic
Compounds. Italian Pat. Appl. N. 19992 A/83. US
Patent N. 4,632,742
France Pat. N. 83 10021 Europe Pat. Appl. N. 84
102310.4 Canada Pat. Appl. N. 449.007 Japan Pat.
Appl. N. 463.78/1984
8. Tundo, P.: Continuous Process for Decomposing
and Decontaminating
Organic Compound and Halogenated Toxic Agents.
Italian Pat. Appl. N. 22215 A/83. European Pat.
Appl. N. 84.1085970 Canada Pat. Appl. N. 459.464
Japan Pat. Appl. N. 1522757/1984 US Pat. Appl.
N. 632.718 (c-i-p N. 916.533).
9. Tundo, P.: New Reagents and Methods for the
Chemical Decomposition of Halogenated Organic
Compounds and Polyhalogenated Toxics and Supertoxics;
Decontamination of Surfaces Polluted by Said Compounds.
Italian Pat. Appl. N. 24443 A/83.
10. Angeletti, E.; Tundo, P.; Venturello, P. and
Fontana, M.: Very Polar Onium Salts Immobilized
on a Very Polar Matrix; Process for Their Preparation.
Italian Pat. Appl. N. 19511 A/84
11. Trotta, F. and Tundo, P.: Process for the
Mono-N-Alkylation of Aromatic Amines with Dialkylcarbonates
Under Gas-Liquid Phase- Transfer Catalysis Conditions.
Italian Pat. Appl. N. 21568 A/85
12. Trotta, F.; Tundo, P. and R. Canavesi, R.:
Process for the
Etherification of Phenols and the Thioetherification
of Mercaptans with
Dialkylcarbonates Under Gas-Liquid Phase-Transfer
Catalysis Conditions.
Italian Pat. Appl. N. 20611 A/86
13. Angeletti, E.; Tundo, P.; Trotta, F. and Venturello,
P.: Continuous
Process for the Alkylation of CH-Acidic Compounds
Under Gas-Liquid
Phase-Transfer Catalysis Conditions. Italian Pat.
Appl. N. 19971 A/86 (3 Aprile 1986) European Pat.
0240863 Canada Pat. Appl. N. 533.654 (Apr. 3 1986)
US Pat. 1990, 4,894,491 Japan Pat. Appl. N. 62-240644
(Oct. 21 1987)
14. Tundo, P.; Tumiatti, W. and Nobile, G.: New
Method for the Improved Chemical Decomposition
of Toxic Halogenated Compound with a U.V. Source.
Italian Pat. Appl. N. 44327 A/85 European Pat.
Appl. N. 86830238.1 USA Pat. Appl. N. 901.188.
15. Tundo, P.: Decontamination Reagent and Method
for the Treatment of Materials Contaminated with
PCBs and Ohter Halogenated Organic Compounds.
U.S. Pat. Appl. N. 07/365367 (June 13, 1989).
16. Tundo, P., Trotta, F.; Moraglio, G. Processo
per la a- Metilazione di Esteri e Lattoni, Dom.
Brevetto Ital. n. 20159 A/90
17. Tundo, P., Loosen, P., Selva, M., Processo
per la a- Monoalchilazione di Arilacetonitrili,
Dom. Brevetto Ital. 1991, MI91A002137
18. Tundo, P., Loosen, P., Selva, M., Processo
per la a-monometilazione di Arilacetoesteri, Dom.
Brevetto Ital. 1992, MI92A00081.
19. Tundo, P., Loosen, P., Selva, M., A process
for the a- monoalkylation of arylacetonitriles,
arylacetoesters and arylacetic acids, Eur. Pat.
Appl., 92112028.3; U. S. Pat. Appl. N. 07/922140
(July 30, 1992); Jap. Pat. Appl., 4-223302 (1992).
20. Loosen, P.; Tundo, P.; Selva, M.; Processo
per la O-benzilazione de fenoli e la a-mono-C-benzilazione
di acetonitrili ed arialcetoesteri. Dom. Brev.
It. No. MI94AN00020 (04/02/94).
21. Selva, M.; Tundo, P.; Procedimento per la
Preparazione di Diaril e Alchilarilnitrili. Dom.
Brev. It. (October 7, 1996.)
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